Self-Sorting Phenomena in Complex Reaction Systems
年份： 2014
中文摘要:The term "self-sorting"has been discussed extensively during the past decade in chemistry.[1] Usually,"sorting"is defined as a process in which different subunits are controlled with precise constitutional and/or positional order according to certain features or criteria.Thus "self-sorting"refers to not only the ability to distinguish "self"from "nonself",but also the operation completed simultaneously and orthogonally within the mixtures.[2] Intuitively,self-sorting phenomena are very common in biological systems and complex supramolecular systems but rare in synthetic systems.[3] Based on the self-sorting property of molecular clusters,we have proposed a novel synthetic strategy of self-sorting reaction systems,which could also be described as multi-domino routes converging strategy.We have developed an efficient carbon-carbon double bond-forming reaction via homo-coupling of aryl methyl ketones or hetreo-coupling of methyl ketones with β-ketone esters and have investigated novel synthetic methods for some structurally diverse heterocyclic library via self-sorting domino strategy.[4]
机构名称:Key Laboratory of Pesticide & Chemical Biology,Ministry of Education,College of Chemistry,Central China Normal University,Hubei,Wuhan 430079,P. R. China
作者姓名:An-Xin Wu
关键词:self-sorting domino reaction reaction system self-organization
会议名称:中国化学会第29届学术年会
日期:2014-08-04
工作单位:Key Laboratory of Pesticide & Chemical Biology
